57Fe Mossbauer Spectroscopic & Density Functional Theory (DFT) Study on the Interactions of the Metal Ion with Monosaccharides
Book Details
Format
Paperback / Softback
ISBN-10
1611223016
ISBN-13
9781611223019
Publisher
Nova Science Publishers Inc
Imprint
Nova Science Publishers Inc
Country of Manufacture
US
Country of Publication
GB
Publication Date
May 4th, 2011
Print length
48 Pages
Weight
94 grams
Dimensions
21.20 x 13.80 x 0.50 cms
Product Classification:
Materials science
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The fundamental electrical and magnetic interactions between iron ions and biomaterials were investigated using an experimental approach, 57Fe Mössbauer spectroscopy, and ab initio computational methods. A conventional spin-Hamiltonian approach adopted for the data analysis of the Mössbauer data showed that the metal ion in the Fe-chitosan complex is in the high-spin ferric state and that it has an internal magnetic field of approximately 440 kG, at the nucleus. The magnitude of the internal field arises from the predominant Fermi-contact interaction of the high-spin ferric species with N/O ligands. This book proposes a scheme for the Fe-chitosan complex based on the analysis of the experimental data.
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