Fast Liquid-Phase Processes in Turbulent Flows

This book deals with the fundamental laws of passing of fast liquid-phase chemical as well as heat and mass transfer processes in turbulent flows. This book is of value and interest to researchers, engineers, teachers, students and postgraduate students in the field of macrokinetics of fast chemical reactions, chemical physics, theoretical technology, chemistry and technology of high molecular weight compounds in both academia and industry.

This book deals with the fundamental laws of passing of fast liquid-phase chemical as well as heat and mass transfer processes in turbulent flows. The fundamental laws of passing of fast liquid-phase chemical and also heat and mass transfer processes in turbulent flows are considered in the book. Development of a macrokinetics approach is generalized to the analysis of fast chemical reactions mainly based on an example of cationic isobutylene polymerization, which falls into to a new class of liquid-phase processes. The ways of decision of the hydrodynamical, thermal and kinetic movement’s equations of reaction mixture in which the fast exothermic chemical reaction runs are described. The principles and laws of formation of the essentially new mode of quasi-plug-flow mode are considered in turbulent flows ensuring quasi-isothermal conditions in zone reaction. The principles of work and area of industrial use of tubular turbulent devices cylindrical reactor, divergent-covergent reactor, shell-and-tube reactor, and reactor with fractional introduction of reactants are considered.