Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C-H Bond Activation
Softcover reprint of the original 1st ed. 2014
Book Details
Format
Paperback / Softback
Book Series
Springer Theses
ISBN-10
4431562486
ISBN-13
9784431562481
Edition
Softcover reprint of the original 1st ed. 2014
Publisher
Springer Verlag, Japan
Imprint
Springer Verlag, Japan
Country of Manufacture
GB
Country of Publication
GB
Publication Date
Sep 27th, 2016
Print length
74 Pages
Product Classification:
Organometallic chemistryMaterials science
Ksh 16,200.00
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Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium.
Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon-hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C-H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.
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