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New Discoveries on the ß-Hydride Elimination
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New Discoveries on the ß-Hydride Elimination

Softcover Reprint of the Original 1st 2012 ed.

Book Details

Format Paperback / Softback
Book Series Springer Theses
ISBN-10 3662522640
ISBN-13 9783662522646
Edition Softcover Reprint of the Original 1st 2012 ed.
Publisher Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Imprint Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Country of Manufacture DE
Country of Publication GB
Publication Date Aug 23rd, 2016
Print length 122 Pages
Product Classification: Organometallic chemistryCatalysis
Ksh 16,200.00
Werezi Extended Catalogue 0 in stock

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New results have been obtained on: (i) Pd-catalyzed 1,2-migration reactions, (ii) Pd-catalyzed Heck reactions employing heteroaromatic tosylates, (iii) Ni-catalyzed Heck reactions, and (iv) Pd-catalyzed carbonylative Heck reaction.
The work presented in Thomas M. Gøgsig''s thesis deals with the discovery of new metal-catalyzed transformations ranging from Kumada-, Heck- and Suzuki-type reactions. The thesis starts with a formidable introduction to Pd-catalyzed cross-coupling reactions. New results have been obtained on:
(i) Pd-catalyzed 1,2-migration reactions,
(ii) Pd-catalyzed Heck reactions employing heteroaromatic tosylates,
(iii) Ni-catalyzed Heck reactions, and
(iv) Pd-catalyzed carbonylative Heck reaction.
Metal-catalyzed cross-coupling reactions are today a highly competititve field (the 2010 Nobel Prize in Chemistry was awarded "for palladium-catalyzed cross couplings in organic synthesis", the 2001 and 2005 Nobel Prizes in closely related fields). Thomas M. Gøgsig obtained new results in his thesis that will help to improve the outcome of catalytic processes and improve their scope. The results will thus become key references for tomorrow''s new applications. All chapters include insightful discussions and in-depth descriptions of the key principles of these new discoveries.

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