New Gold-Catalyzed Reactions and Applications for the Synthesis of Alkaloids
2013 ed.
Book Details
Format
Hardback or Cased Book
Book Series
Springer Theses
ISBN-10
3319007017
ISBN-13
9783319007014
Edition
2013 ed.
Publisher
Springer International Publishing AG
Imprint
Springer International Publishing AG
Country of Manufacture
GB
Country of Publication
GB
Publication Date
Aug 21st, 2013
Print length
195 Pages
Weight
462 grams
Dimensions
24.30 x 15.70 x 1.70 cms
Product Classification:
Organometallic chemistryCatalysis
Ksh 16,200.00
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Ana Escribano Cuesta's thesis presents a detailed study of the inter- and intramolecular reactions of carbonyl compounds with 1,6-enynes using gold (I) complexes.
Ana Escribano Cuesta's thesis presents a detailed study of the inter- and intramolecular reactions of carbonyl compounds with 1,6-enynes using gold (I) complexes. An important part of the work involved streamlining the variables that allow the selective synthesis of different products such as tricyclic compounds, dihydropyrans, 1,3-dienes or cyclobutenes. The second chapter highlights the importance and difficulties in synthesising a cyclobutene subunit and the author includes a detailed description of how the products were prepared. The final chapter outlines the synthesis of lundurines using methodology developed by the author's research group for intramolecular gold-catalyzed cyclization of indoles with alkynes. The lundurine products developed in this work show significant in vitro cytoxicity toward B16 melanoma cells. The work in this thesis has led to a number of publications in high-profile chemistry journals.
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