Book Details
Format
Hardback or Cased Book
Book Series
Springer Theses
ISBN-10
981157622X
ISBN-13
9789811576225
Edition
2020 ed.
Publisher
Springer Verlag, Singapore
Imprint
Springer Verlag, Singapore
Country of Manufacture
GB
Country of Publication
GB
Publication Date
Aug 11th, 2020
Print length
105 Pages
Weight
312 grams
Dimensions
24.50 x 16.30 x 14.30 cms
Product Classification:
ChemistryOrganic chemistryCatalysisSustainability
Ksh 16,200.00
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This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized a, ß- and ß, ?-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry.
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