Book Details
Format
Paperback / Softback
Book Series
Springer Theses
ISBN-10
9811576254
ISBN-13
9789811576256
Edition
2020 ed.
Publisher
Springer Verlag, Singapore
Imprint
Springer Verlag, Singapore
Country of Manufacture
GB
Country of Publication
GB
Publication Date
Aug 12th, 2021
Print length
105 Pages
Weight
198 grams
Dimensions
23.30 x 15.50 x 1.10 cms
Product Classification:
ChemistryOrganic chemistryCatalysisSustainability
Ksh 16,200.00
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This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized a, ß- and ß, ?-unsaturated carboxylic acids. The findings presented not only enrich the field of ''C1 chemistry,'' but also support the advancement of green and sustainable chemistry.
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