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Th Thorium : Compounds with Carbon: Carbonates, Thiocyanates, Alkoxides, Carboxylates - 8th ed. 1988. Softcover reprint of the original 8t

By: (Author) Kenneth W. Bagnall

Extended Catalogue

Ksh 9,200.00

Format: Paperback / Softback

ISBN-10: 3662063174

ISBN-13: 9783662063170

Edition: 8th ed. 1988. Softcover reprint of the original 8t

Series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition

Publisher: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG

Imprint: Springer-Verlag Berlin and Heidelberg GmbH & Co. K

Country of Manufacture: DE

Country of Publication: GB

Publication Date: Oct 3rd, 2013

Print length: 163 Pages

Product Classification: Inorganic chemistry

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The present volume of the Gmelin thorium series describes the solid thorium-carbon compounds with the exception of the carbides and coordination compounds of the type 4 ThAn· X B, where B is a neutral ligand.
The present volume of the Gmelin thorium series describes the solid thorium-carbon compounds with the exception of the carbides and coordination compounds of the type 4 ThAn· X B, where B is a neutral ligand. The complex equilibria of the Th + ion with C-containing complexing agents are treated in the ThD1 volume. A first look into this volume demonstrates that a very large number of ThlV complexes has 4 been prepared. This may be explained by the fact that the Th + ion is the largest tetravalent ion of the periodic table. Therefore, the preparation of complexes with, e. g. , multidentate ligands can give a well-established picture of the coordination number as a function of charge and ionic radius. However, there are very few modern and updated comprehensive treatments of such data. Many compounds described in this volume are characterized by no other means than analytical composition and IR spectra (whereby IR spectra of organic ThlV salts mostly give information only on the ligand). Besides thorium carbonate and carbonato complexes, which are relevant for the environmental behaviour of this radioactive element and some organic complexes like oxalates, which are used in the field of analytical and separation chemistry nearly all other compounds described here are practically only of scientific interest. On the other hand in order to have scientifically reliable data, a very large part of these compounds needs further investigation and characterization.

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